Newham, G. orcid.org/0000-0002-4877-5513, Fox, J., Moorcroft, S.C.T. et al. (1 more author) (2023) Enzymatic and catalytic behaviour of low-dimensional gold nanomaterials in modular nano-composite hydrogels. Materials Research Express, 10 (6). ARTN 064001. ISSN 2053-1591
Abstract
Inorganic nanoparticles have long been applied as catalysts and nanozymes with exceptional rate constants arising from their large surface areas. While it is understood that high surface area-to-volume ratios and low average atomic coordination are responsible for their exceptional catalytic properties, these facets remain under exploited in the design of gold nanoparticle catalysts and nanozymes. Here we have developed 3D, 2D, and quasi-1D gold nanoparticles for use as catalysts in reducing 4-nitrophenol by sodium borohydride. Each morphology was characterised with transmission electron microscopy and UV–vis absorption spectroscopy, while the highest catalytic activity was achieved when the perimeter-to-surface area, or amount of 'edge', was maximised. The particles were then applied as nanozymes in modular nano-composite hydrogels. Independent hydrogel tiles containing either the substrate or catalyst were bonded in stacks, which allowed reagent transport across their interface for the colourimetric detection of hydrogen peroxide. This work presents novel insight into the catalytic activity of low-dimension nanoparticles and their potential application in nanozyme-based diagnostic devices.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2023 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. |
Keywords: | enzymatic; catalytic; behaviour; low-dimensional; gold; nanomaterials |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Physics and Astronomy (Leeds) > Molecular & Nanoscale Physics |
Depositing User: | Symplectic Publications |
Date Deposited: | 30 Jan 2024 11:00 |
Last Modified: | 30 Jan 2024 11:09 |
Published Version: | https://iopscience.iop.org/article/10.1088/2053-15... |
Status: | Published |
Publisher: | IOP Publishing |
Identification Number: | 10.1088/2053-1591/acdc05 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:208429 |