Cross aldol OPAL bioconjugation outcompetes intramolecular hemiaminal cyclisation of proline adjacent N-terminal α-oxo aldehydes at acidic pH

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Item Type:	Article
Authors/Creators:	Tufail, Afzaal Akkad, Saeed https://orcid.org/0000-0002-7271-0496 Hatton, Natasha (natasha.hatton@york.ac.uk) Yates, Nick (nicholas.yates@york.ac.uk) Spears, Richard (rjs540@york.ac.uk) Keenan, Tessa (tessa.keenan@york.ac.uk) Parkin, Alison https://orcid.org/0000-0003-4715-7200 Signoret, Nathalie Yvonne Micheline https://orcid.org/0000-0003-4977-4149 Fascione, Martin Anthony https://orcid.org/0000-0002-0066-4419
Copyright, Publisher and Additional Information:	© 2024 The Author(s).
Dates:	Accepted: 12 January 2024 Published (online): 24 January 2024
Institution:	The University of York
Academic Units:	The University of York > Faculty of Sciences (York) > Hull York Medical School (York) The University of York > Faculty of Sciences (York) > Chemistry (York)
Funding Information:	Funder Grant number EUROPEAN COMMISSION 101044024
Depositing User:	Pure (York)
Date Deposited:	17 Jan 2024 10:00
Last Modified:	20 Sep 2025 02:09
Published Version:	https://doi.org/10.1039/d3ra08776j
Status:	Published online
Refereed:	Yes
Identification Number:	10.1039/d3ra08776j
Open Archives Initiative ID (OAI ID):	oai:eprints.whiterose.ac.uk:207793

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Description: Cross aldol OPAL bioconjugation outcompetes intramolecular hemiaminal cyclisation of proline adjacent N-terminal a-oxo aldehydes at acidic pH

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