Alanazi, M., Ries, M.E. orcid.org/0000-0002-8050-3200 and Hine, P.J. (Cover date: September 2023) Dissolution of viscose rayon multifilament yarn in the ionic liquid 1-ethyl-3-methylimidazolium acetate studied using time–temperature superposition. Cellulose, 30. pp. 8739-8751. ISSN 0969-0239
Abstract
Wide-angle X-ray diffraction (WAXS) and mechanical testing techniques are used to track the dissolution of a viscose rayon multifilament yarn in the ionic liquid 1-ethyl-3-methyl-imidazolium acetate [C2mim]+ [OAc]− for different times and temperatures. In the dissolution process, the oriented cellulose II crystals in the regenerated cellulose fibres dissolve and then reform into randomly oriented crystals to form a matrix phase, and this change in orientation enables us to follow the dissolution process using WAXS, and hence determine the dissolved matrix volume fraction vm . The change in the average molecular orientation P2 determined from an azimuthal (α ) X-ray scan, allows the growth of the matrix volume fraction vm to be calculated with time and temperature. The growth of vm was found to follow time temperature superposition, with an Arrhenius behaviour, giving a value for the activation energy of Ea = 149 ± 4 kJ/mol. Young’s modulus was measured on all the resulting processed composites. The fall of Young’s modulus with dissolution time and temperature was also found to follow time–temperature superposition, with an Arrhenius behaviour giving a value for Ea = 198 ± 29 kJ/mol. The Young’s Modulus results plotted against vm determined from the WAXS measurements fitted well to the Voigt upper bound parallel Rule of Mixtures .
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © The Author(s) 2023. This is an open access article, under the terms of the Creative Commons Attribution License (CC-BY 4.0), which permits unrestricted use, distribution and reproduction in any medium, provided the original work is properly cited. |
Keywords: | Rayon; Ionic liquid; Time-temperature superposition (tts) |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Physics and Astronomy (Leeds) > Soft Matter Physics (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 21 Sep 2023 09:19 |
Last Modified: | 21 Sep 2023 09:19 |
Status: | Published |
Publisher: | Springer |
Identification Number: | 10.1007/s10570-023-05362-x |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:203543 |