El-Shinawi, H. orcid.org/0000-0002-4743-5576, Cussen, E.J. orcid.org/0000-0002-2899-6888 and Corr, S.A. orcid.org/0000-0002-9303-4220 (2019) Morphology-directed synthesis of LiFePO4 and LiCoPO4 from nanostructured Li1+2xPO3+x. Inorganic Chemistry, 58 (10). pp. 6946-6949. ISSN 0020-1669
Abstract
A LiPO3-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO4 and LiCoPO4, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2019 American Chemical Society. This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
Dates: |
|
Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Chemical and Biological Engineering (Sheffield) |
Funding Information: | Funder Grant number ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/N001982/1 ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL EP/R030480/2 Engineering and Physical Sciences Research Council EP/N001982/2 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 27 Apr 2023 14:25 |
Last Modified: | 27 Apr 2023 14:25 |
Published Version: | http://dx.doi.org/10.1021/acs.inorgchem.9b00517 |
Status: | Published |
Publisher: | American Chemical Society (ACS) |
Refereed: | Yes |
Identification Number: | 10.1021/acs.inorgchem.9b00517 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:198577 |