Danso-Boateng, E, Fitzsimmons, M, Ross, AB et al. (1 more author) (Cover date: March 1 2023) Response Surface Modelling of Methylene Blue Adsorption onto Seaweed, Coconut Shell and Oak Wood Hydrochars. Water, 15 (5). 977. ISSN 2073-4441
Abstract
Adsorption of methylene blue (MB) dye from an aqueous solution onto hydrochars produced from brown seaweed (Fucus Serratus) (FS-HC), coconut shell (CS-HC), and oak wood (Oak-HC) at different temperatures (200–250 °C) was investigated in a batch system. Response surface modelling (RSM) was used to investigate the effect of initial MB concentration (50–300 mg/L), contact time (0–240 min), and solution pH (2–12) on the adsorption process. RSM was also used to model and optimise these parameters for efficient adsorption. Kinetic and isotherms studies were carried out to study the adsorption mechanism onto the hydrochars. It was found that the best adsorbent from the RSM model was FS-HC200, and the optimal conditions for greater MB dye uptake were lower initial MB concentration (50 mg/L), pH 6 and contact time of 84 min; removing >99% of MB. Langmuir and Redlich–Peterson isotherm models fitted the adsorption of MB onto hydrochars prepared at 200 and 250 °C. Freundlich and Redlich–Peterson isotherms were suitable for hydrochars produced at 220 °C. FS-HCs have the highest maximum adsorption capacity of MB of about (8.60–28.57) mg/g calculated from the Langmuir isotherm. The adsorption process for all the hydrochars followed a pseudo-second-order model (R² = 0.96–1.00), and film diffusion and intraparticle diffusion were the rate-determining steps. Therefore, this work identifies cheap adsorbents from biowaste that are effective for the removal of cationic pollutants from wastewater.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
Keywords: | Fucus Serratus; hydrochar; hydrothermal carbonisation; methylene blue; response surface modelling; seaweed; wastewater treatment |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Funding Information: | Funder Grant number BBSRC (Biotechnology & Biological Sciences Research Council) BB/S011439/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 03 Apr 2023 09:34 |
Last Modified: | 03 Apr 2023 09:34 |
Status: | Published |
Publisher: | MDPI AG |
Identification Number: | 10.3390/w15050977 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:197930 |