Al-Rahbi, AS and Williams, PT orcid.org/0000-0003-0401-9326 (2022) Decomposition of biomass gasification tar model compounds over waste tire pyrolysis char. Waste Disposal & Sustainable Energy, 4 (2). pp. 75-89. ISSN 2524-7980
Abstract
Gasification of biomass produces a syngas containing trace amounts of viscous hydrocarbon tar, which causes serious problems in downstream pipelines, valves and processing equipment. This study focuses on the use of tire-derived pyrolysis char for tar conversion using biomass tar model compounds representative of tar. The catalytic decomposition of tar model compounds, including methylnaphthalene, furfural, phenol, and toluene, over tire char was investigated using a fixed bed reactor at a bed temperature of 700 °C and 60 min time on stream. The influence of temperature, reaction time, porous texture, and acidity of the tire char was investigated with the use of methylnaphthalene as the tar model compound. Oxygenated tar model compounds were found to have higher conversion than those containing a single or multi-aromatic ring. The reactivity of tar compounds followed the order of furfural > phenol > toluene > methylnaphthalene. The conversion of the model compounds in the presence of the tire char was much higher than tar thermal cracking. Gas production increased dramatically with the introduction of tire char. The H2 potential for the studied tar model compounds was found to be in the range of 40%–50%. The activity of tire char for naphthalene removal was compared with two commercial activated carbons possessing a very well-developed porous texture. The results suggest that the influence of Brunauer-Emmett-Teller surface area of the carbon on tar cracking is negligible compared with the mineral content in the carbon samples.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © The Author(s) 2022. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. |
Keywords: | Biomass; Gasifcation; Syngas; Tar; Tire; Char |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 10 Mar 2023 09:56 |
Last Modified: | 25 Jun 2023 23:16 |
Status: | Published |
Publisher: | Springer |
Identification Number: | 10.1007/s42768-022-00103-5 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:197178 |