Soultati, A., Nunzi, F., Fakharuddin, A. orcid.org/0000-0001-5589-4265 et al. (22 more authors) (2022) Functionalized BODIPYs as tailor‐made and universal interlayers for efficient and stable organic and perovskite solar cells. Advanced Materials Interfaces, 9 (21). 2102324. ISSN 2196-7350
Abstract
Solar cells based on metal halide perovskite and polymer donor:nonfullerene acceptor blend absorbers have recently witnessed a significant rise in their photovoltaic performance. However, they still suffer from some instability issues originating from the inferior interface quality and poor nanomorphology of the absorber layer. In this work, a series of functionalized boron-dipyrromethene, BODIPY, molecules are introduced as ultrathin interlayers at the absorber/electron transport layer interface. This study indicates that BODIPY compounds with a high molecular dipole moment can enhance the device performance mainly due to better interface energy level alignment. They also induce passivation of defect traps and improvement in the charge transport properties of the absorber layer coated on top of them. Among the various compounds used, amino-functionalized BODIPY, owing to the synergetic effect of the abovementioned factors, enables the highest power conversion efficiency in organic (15.69%) as well as in perovskite solar cells (20.12%). Amino-functionalized BODIPY also demonstrates an enhanced stability under continuous illumination (in nitrogen) without and with heating (at 65 °C) for 1000 h. These results pave the way for the implementation of molecules with tailor-made functionalities in high efficiency and stable solution-based photovoltaic devices of the future.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2022 Wiley-VCH GmbH. This is an author-produced version of a paper subsequently published in Advanced Materials Interfaces. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | absorber layer morphology; charge transfer; interfacial recombination; stability of organic solar cells; work function |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Chemical and Biological Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 02 Mar 2023 16:39 |
Last Modified: | 24 Jun 2023 00:13 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1002/admi.202102324 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:196943 |