Laverick, RJ orcid.org/0000-0003-1840-871X, Zhang, N, Reid, E et al. (3 more authors) (2021) Solution processible Co(III) quinoline-thiosemicarbazone complexes: synthesis, structure extension, and Langmuir-Blodgett deposition studies. Journal of Coordination Chemistry, 74 (1-3). pp. 321-340. ISSN 0095-8972
Abstract
Seven readily synthesized 8-quinoline-4-R-3-thiosemicarbazone ligands [where R = phenyl (L1H), 4-fluorophenyl (L2H), 4-iodophenyl (L3H), 4-nitrophenyl (L4H), 4-carboxyphenyl (L5H), 3-picolyl (L6H), and octadecyl (L7H)], and their corresponding Co(III) coordination complexes, [Co(L)2]BF4, have been synthesized and characterized. Crystallographic analysis of the complexes revealed that the substituents significantly alter solid-state supramolecular network topologies. The solution processability of these complexes was confirmed by incorporating a long carbon alkyl-chain into the ligand (L7H) and immobilizing the complex onto quartz slides using Langmuir-Blodgett deposition. The facile and modular synthesis of these thiosemicarbazone-based ligands coupled with the potential to exploit multiple applications makes these compounds excellent candidates for functional supramolecular materials.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2021 Informa UK Limited, trading as Taylor & Francis Group. This is an author produced version of an article published in Journal of Coordination Chemistry. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | Thiosemicarbazone; cobalt (III); supramolecular materials; Langmuir-Blodgett; structure extension |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Physical Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 11 Jan 2023 17:03 |
Last Modified: | 01 Apr 2023 01:46 |
Published Version: | http://dx.doi.org/10.1080/00958972.2021.1879384 |
Status: | Published |
Publisher: | Taylor and Francis Group |
Identification Number: | 10.1080/00958972.2021.1879384 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:194929 |