Haslewood, Marcell N.D., Farmer, Thomas J. orcid.org/0000-0002-1039-7684 and North, Michael orcid.org/0000-0002-6668-5503 (2022) Synthesis and chemoselective crosslinking of functionalized polyesters from bio-based epoxides and cyclic anhydrides. Journal of Polymer Science. ISSN 2642-4169
Abstract
Biomass derivable epichlorohydrin undergoes ring-opening copolymerization with either succinic or itaconic anhydride (both biosourcable) under standard laboratory conditions using metal-based or an entirely organic initiator to form highly functionalized, low molecular weight polyesters. The linear polyesters obtained from epichlorohydrin and itaconic anhydride contain both alkyl chlorides and α,β-unsaturated esters and can be crosslinked to form insoluble resins by treatment with di- to tetra-functional amines and thiols. Crosslinking with amines predominately occurs through the alkyl chlorides whilst crosslinking with thiols occurs through the α,β-unsaturated esters allowing the synthesis of insoluble polyester derived resins with complementary and controllable functionalities.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2022 The Authors. |
Keywords: | anhydride,bio-derivable,cross-link,epoxide,ring-opening copolymerization |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 04 Nov 2022 10:30 |
Last Modified: | 16 Oct 2024 18:50 |
Published Version: | https://doi.org/10.1002/pol.20220552 |
Status: | Published online |
Refereed: | Yes |
Identification Number: | 10.1002/pol.20220552 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:192978 |
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