Plane, JMC orcid.org/0000-0003-3648-6893 and Robertson, SH (2022) Master Equation Modelling of Non-equilibrium Chemistry in Stellar Outflows. Faraday Discussions, 238. pp. 461-474. ISSN 1359-6640
Abstract
A current challenge in astrochemistry is to explain the formation of Fe–Mg silicate dust around evolved stars. The dust is observed to form within 2 to 3 stellar radii of oxygen-rich AGB stars, where the typical conditions are kinetic (translational) temperatures between 1200 and 1600 K, and total gas densities below 10₁₁ cm⁻³. At these high temperatures, molecules with bond energies < 400 kJ mol⁻¹ should be short-lived, and this results in kinetic bottlenecks in postulated mechanisms for converting the observed Fe, Mg, SiO and H₂O into silicate. Here we show that, in the very low pressure regime of a stellar outflow, molecules can exhibit significant vibrational disequilibrium because optical transitions – both spontaneous and stimulated by the stellar radiation field – occur on a much faster timescale than collisions. As a result, relatively less stable molecules can form and survive long enough to provide building blocks to silicate formation. Here we use the molecule OSi(OH)₂, formed by the recombination of SiO₂ and H₂O, as an example. When vibrational disequilibrium is accounted for in a master equation treatment which includes optical transitions, the quantity of metal silicates produced in a low mass loss rate evolved star (R Dor) is increased by 6 orders of magnitude.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2022. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Physical Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 18 Feb 2022 15:14 |
Last Modified: | 16 Mar 2023 01:53 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/D2FD00025C |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:183746 |