Jha, A orcid.org/0000-0003-3150-5645 and Lahiri, A (2022) Accelerated Electro-Reduction of TiO2 to Metallic Ti in a CaCl2 Bath Using an Inert Intermetallic Anode. Journal of the Indian Institute of Science, 102 (1). pp. 127-137. ISSN 0970-4140
Abstract
In the FFC-Cambridge process, the cathodic dissociation of oxide and CO/CO2 production on carbon anode is the basis for metal production in a CaCl2 bath. Using an inert intermetallic anode, the CO2 evolution can be eliminated altogether with acceleration in the electro-reduction kinetics. In the presence of a carbon anode, the cathodic dissociation of TiO2 suffers from slow reduction kinetics of TiO2 to Ti metal, which can be enhanced significantly by the incorporation of alkali species in the TiO2 pellet at the cathode and in the CaCl2 bath in the presence of an intermetallic inert anode. With inert anode and incorporation of K+-ion in the TiO2 matrix and in the salt bath, nearly full metallization with greater than 99% of Ti metal containing 1500 ppm of oxygen was possible to achieve in less than 16 h of electro-reduction. The microstructural and chemical analysis of the metallic phase and its morphology revealed the presence of a layer of titanium metal that forms in the fast reduction reaction step in less than 5 h, after which the reaction rate slows down significantly before terminating in 16 h. The investigation showed that two different types of microstructures of metallic titanium were evident—a thin sheet-like material on the outer periphery of the reduced pellet and the dendritic core which was found to be under the peripheral sheet of the metallic layer. The mechanism of morphological and microstructural changes in the reduced form of titanium metal is explained.
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Item Type: | Article |
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Copyright, Publisher and Additional Information: | © Crown 2022. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Funding Information: | Funder Grant number EPSRC (Engineering and Physical Sciences Research Council) EP/C007581/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 31 Jan 2022 15:23 |
Last Modified: | 28 Jun 2022 08:57 |
Status: | Published |
Publisher: | Springer Nature |
Identification Number: | 10.1007/s41745-022-00296-y |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:183051 |
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