Aslam, A., Rehman, A.U., Amin, N. et al. (9 more authors) (2022) Sol–Gel Auto-combustion Preparation of M2+ = Mg2+, Mn2+, Cd2+ Substituted M0.25Ni0.15Cu0.25Co0.35Fe2O4 Ferrites and Their Characterizations. Journal of Superconductivity and Novel Magnetism, 35 (2). pp. 473-483. ISSN 1557-1939
Abstract
Cost-effective and controllable synthesis of M0.25Ni0.15Cu0.25Co0.35Fe2O4 (M2+ = Mg2+, Mn2+, and Cd2+) ferrites via the sol–gel auto-combustion technique. The impact of divalent cations on the structural, dielectric, and optoelectrical properties of ferrites was examined by XRD, FTIR, Raman, LCR, UV–Vis, and two probe I-V measurement techniques. The crystallite size was 52.66 nm, and the minimum specific surface area was observed 5.1507 m2/g for Mg2+ doped NCCF ferrite. The FTIR and Raman analysis also confirmed the substitution of divalent cations (M2+ = Mg2+, Mn2+, and Cd2+) at their respective lattice sites. The maximum energy bandgap was 1.67 eV Mg2+-doped NCCF ferrite as compared to other divalent ion-doped ferrites. The dielectric loss decreased while the ac conductivity increased with increasing frequency, and the minimum values were observed for Mg2+-doped NCCF ferrite. The activation energy was observed maximum for Mg2+-doped NCCF ferrite (0.2234 eV). Due to incredible properties including small specific surface area, large energy band gap, high resistivity, and loss dielectric loss of Mg2+-doped NCCF ferrite have potential applications in different fields.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021. This is an author-produced version of a paper subsequently published in Journal of Superconductivity and Novel Magnetism. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | Divalent; Specific surface area; Energy band; Raman; Activation energy |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 24 Jan 2022 09:32 |
Last Modified: | 13 Nov 2022 01:13 |
Status: | Published |
Publisher: | Springer Science and Business Media LLC |
Refereed: | Yes |
Identification Number: | 10.1007/s10948-021-06085-5 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:182849 |