Nicholls, TP orcid.org/0000-0001-6654-0825, Burt, LK, Simpson, PV et al. (2 more authors) (2019) Tricarbonyl rhenium(i) tetrazolato and N-heterocyclic carbene complexes: versatile visible-light-mediated photoredox catalysts. Dalton Transactions, 48 (33). pp. 12749-12754. ISSN 1477-9226
Abstract
We have investigated the capacity of a range of structurally-diverse, photoactive rhenium(I) tricarbonyl complexes featuring either tetrazolato or N-heterocyclic carbene (NHC) ligands to facilitate fundamental classes of visible-light-mediated photoredox-catalysed reactions. In this study, we demonstrate that these systems mediate representative atom-transfer radical addition, hydrodehalogenation, and α-amino C–H functionalisation reactions. These rhenium(I) complexes provide greater or at least comparable reactivity to the prototypical photoredox catalyst [Ru(bpy)3]2+ in many cases.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 24 Nov 2021 10:06 |
Last Modified: | 24 Nov 2021 10:06 |
Status: | Published |
Publisher: | Royal Society of Chemistry (RSC) |
Identification Number: | 10.1039/c9dt02533b |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:180660 |