Lin, L., Miao, N., Wallace, G.G. et al. (2 more authors) (2021) Engineering carbon materials for electrochemical oxygen reduction reactions. Advanced Energy Materials, 11 (32). 2100695. ISSN 1614-6832
Abstract
The electrochemical oxygen reduction reaction (ORR) is the key energy conversion reaction involved in fuel cells, metal-air batteries, and hydrogen peroxide production. Proliferation and improvement of the ORR requires wider use of new and existing high performance catalysts; unfortunately, most of these are still based on precious metals and become uneconomical in mass-use applications. Recent progress suggests that low cost and durable carbon materials can potentially be developed as efficient ORR catalysts. Significant efforts have been made in discovering fundamental catalytic mechanisms and engineering techniques to guide and enable viable regulation of both the ORR activity and selectivity of these carbon catalysts. Starting from the fundamental understanding, this report reviews recent progress in engineering carbon materials from exotic chemical doping to intrinsic geometric defects for improved ORR. On the basis of both theoretical and experimental investigations reported so far in this area, future improvements in carbon catalysts are also discussed, providing useful pathways for more efficient and reliable energy conversion technologies.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | © 2021 Wiley-VCH GmbH. This is an author-produced version of a paper subsequently published in Advanced Energy Materials. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | adsorption energy; carbon materials; density functional theory; electronic structure; oxygen reduction reaction |
Dates: |
|
Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 13 Aug 2021 10:53 |
Last Modified: | 14 Jul 2022 00:14 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1002/aenm.202100695 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:177089 |