Galadzhun, I orcid.org/0000-0002-0512-3830, Kulmaczewski, R orcid.org/0000-0002-3855-4530, Shahid, N orcid.org/0000-0002-8090-7619 et al. (3 more authors) (2021) The flexibility of long chain substituents influences spin-crossover in isomorphous lipid bilayer crystals. Chemical Communications. ISSN 1359-7345
Abstract
[Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives bearing a bent geometry of hexadec-1-ynyl or hexadecyl substituents pyrazole are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt, stepwise spin-transition on cooling. This may reflect the different conformational flexibilities of their long chain substituents.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry. This is an author produced version of a journal article published in Chemical Communications. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Funding Information: | Funder Grant number EPSRC (Engineering and Physical Sciences Research Council) EP/K012568/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 23 Mar 2021 17:38 |
Last Modified: | 08 Jan 2025 14:40 |
Status: | Published online |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/d1cc01073e |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:172417 |