Gardner, L.J. orcid.org/0000-0003-3126-2583, Corkhill, C.L. orcid.org/0000-0002-7488-3219, Walling, S.A. et al. (5 more authors) (2021) Early age hydration and application of blended magnesium potassium phosphate cements for reduced corrosion of reactive metals. Cement and Concrete Research, 143. 106375. ISSN 0008-8846
Abstract
Magnesium potassium phosphate cements (MKPC) were investigated to determine their efficacy towards retardation of reactive uranium metal corrosion. Optimised low-water content, fly ash (FA) and blast furnace slag (BFS) blended MKPC formulations were developed and their fluidity, hydration behaviour, strength and phase assemblage investigated. In-situ time resolved synchrotron powder X-ray diffraction was used to detail the early age (~60 h) phase assemblage development and hydration kinetics, where the inclusion of BFS was observed to delay the formation of struvite-K by ~14 h compared to FA addition (~2 h). All samples set within this period, suggesting the possible formation of a poorly crystalline binding phase prior to struvite-K crystallisation. Long-term corrosion trials using metallic uranium indicated that MKPC systems are capable of limiting uranium corrosion rates (reduced by half), when compared to a UK nuclear industry grout, which highlights their potential application radioactive waste immobilisation.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2021 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
Keywords: | Chemically bonded ceramics (D); Calorimetry (A); Hydration (A); X-ray diffraction (B); Radioactive waste (E) |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number Engineering and Physical Science Research Council EP/N017617/1; EP/N017374/1; EP/P013600/1; EP/S032959/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 09 Mar 2021 08:54 |
Last Modified: | 09 Mar 2021 08:54 |
Status: | Published |
Publisher: | Elsevier BV |
Refereed: | Yes |
Identification Number: | 10.1016/j.cemconres.2021.106375 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:171072 |