Shimizu, Seishi orcid.org/0000-0002-7853-1683 and Matubayasi, Nobuyuki (2021) Implicit function theorem and Jacobians in solvation and adsorption. Physica A: Statistical Mechanics and its Applications. 125801. ISSN 0378-4371
Abstract
The use of Jacobians in chemical thermodynamics has focused chiefly on explicit functions. We generalize this powerful method to incorporate implicit functions. Considering a slight deviation from equilibrium, governed by the Gibbs-Duhem equations, is demonstrated to simplify the theories of preferential solvation and adsorption significantly. Since these deviations are zero at equilibrium, implicit function theorem can be applied by postulating their differentiability. A generalization to multiple component solutions is straightforward by virtue of Jacobians and the implicit function theorem.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | ©2021 Elsevier B.V.All rights reserved.This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 01 Feb 2021 16:30 |
Last Modified: | 01 Mar 2025 00:07 |
Published Version: | https://doi.org/10.1016/j.physa.2021.125801 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1016/j.physa.2021.125801 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:170621 |