Griggs, S, Roncero, AM, Nelson, A et al. (1 more author) (2020) Regioselective side-chain amination of 2-alkyl azacycles by radical translocation: total synthesis of tetraponerine T8. Chemical Communications. ISSN 1359-7345
Abstract
The regioselective γ-C–H amination of the side-chain of saturated 2-alkyl nitrogen heterocycles is reported, proceeding through a sulfamide-directed 1,6-radical translocation. The practicality of this rapid access to 1,3-diamines is highlighted in a short synthesis of the alkaloid tetraponerine T8 and non-natural analogues.
Metadata
| Item Type: | Article |
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| Authors/Creators: |
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| Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2020. This is an author produced version of an article published in Chemical Communications. Uploaded in accordance with the publisher's self-archiving policy. |
| Dates: |
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| Institution: | The University of Leeds |
| Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
| Depositing User: | Symplectic Publications |
| Date Deposited: | 06 Jan 2021 12:39 |
| Last Modified: | 18 Dec 2021 01:38 |
| Status: | Published online |
| Publisher: | Royal Society of Chemistry (RSC) |
| Identification Number: | 10.1039/d0cc07625b |
| Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:169240 |

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