Li, S, Yu, S, Collins, SM orcid.org/0000-0002-5151-6360 et al. (9 more authors) (2020) A New Route to Porous Metal-Organic Framework Crystal-Glass Composites. Chemical Science. ISSN 2041-6520
Abstract
Metal-organic framework crystal-glass composite (MOF-CGC) materials consist of a crystalline MOF embedded within a MOF-glass matrix. In this work, a new synthetic route to these materials is demonstrated through the preparation of two ZIF-62 glass-based CGCs, one with crystalline ZIF-67 and the other with crystalline UiO-66. Previous attempts to form these CGCs failed due to the high processing temperatures involved in heating above the melting point of ZIF-62. Annealing of the ZIF-62 glass above the glass transition with each MOF however leads to stable CGC formation, at lower temperatures. The reduction in processing temperatures will enable the formation of a greatly expanded range of MOF-CGCs.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 02 Sep 2020 15:03 |
Last Modified: | 02 Sep 2020 15:03 |
Status: | Published online |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/d0sc04008h |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:164929 |