Rossi-Ashton, James A., Clarke, Aimee K., Unsworth, William P. orcid.org/0000-0002-9169-5156 et al. (1 more author) (2020) Phosphoranyl Radical Fragmentation Reactions Driven by Photoredox Catalysis. ACS Catalysis. pp. 7250-7261. ISSN 2155-5435
Abstract
Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method for the generation of diverse and valuable radicals, typically via deoxygenation or desulfurization processes. This Perspective is a comprehensive evaluation of all studies using phosphoranyl radicals as tunable mediators in photoredox catalysis, highlighting how two distinct methods for phosphoranyl radical formation (radical addition and nucleophilic addition) can be used to generate versatile radical intermediates with diverse reactivity profiles.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 American Chemical Society |
Keywords: | phosphine,phosphoranyl,photoredox,radical,visible light |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Funding Information: | Funder Grant number EPSRC EP/R013748/1 |
Depositing User: | Pure (York) |
Date Deposited: | 28 Jul 2020 13:20 |
Last Modified: | 17 Dec 2024 00:16 |
Published Version: | https://doi.org/10.1021/acscatal.0c01923 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1021/acscatal.0c01923 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:163811 |