Schotten, C, Leprevost, SK, Yong, LM et al. (3 more authors) (2020) Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes. Organic Process Research & Development. ISSN 1083-6160
Abstract
A range of diazonium salts and their corresponding triazenes have been prepared in order to directly compare their relative thermal stabilities (via initial decomposition temperature) from differential scanning calorimetry (DSC) data. A structure–stability relationship has been explored to investigate trends in stability, depending on the aromatic substituent and the structure of the secondary amine component of the diazonium salts and triazenes. All of the triazenes investigated show significantly greater stability (many are stable above 200 °C) compared with the corresponding diazonium salts, which show varying stabilities.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 American Chemical Society. This is an author produced version of an article published in Organic Process Research & Development. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | triazene; diazonium salt; thermal stability |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 25 Jun 2020 14:58 |
Last Modified: | 21 May 2021 00:38 |
Status: | Published online |
Publisher: | American Chemical Society |
Identification Number: | 10.1021/acs.oprd.0c00162 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:162397 |