Mottram, L.M., Stennett, M.C. orcid.org/0000-0002-8363-9103, Sun, S.K. et al. (1 more author) (2020) Laboratory based X-ray absorption spectroscopy of iron phosphate glasses for radioactive waste immobilisation: a preliminary investigation. In: IOP Conference Series: Materials Science and Engineering. THERAMIN 2020 conference: thermal treatment of radioactive waste, 04-05 Feb 2020, Manchester, UK. IOP Publishing
Abstract
We report the application of laboratory based X-ray absorption spectroscopy to the speciation of Fe in iron phosphate glasses prepared by conventional and microwave melting. Analysis of the weak pre-edge features in Fe K-edge XANES data demonstrated glasses produced by microwave melting to have a higher fraction of reduced Fe2+ species, since microwave melts do not have sufficient time to equilibrate with the prevailing oxygen partial pressure, compared to counterparts produced by conventional melting. Furthermore, our laboratory XANES data are consistent with the formation of octahedral Fe2+ at the expense of tetrahedral Fe3+ species, with increasing Fe2+ content. These findings are consistent with the previous findings of our 57Fe Mossbauer study, synchrotron XANES data, and current understanding of the structure of iron phosphate glasses, and demonstrate the utility of laboratory based XANES for routine speciation of Fe in these and other materials.
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Item Type: | Proceedings Paper |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020 Published under licence by IOP Publishing Ltd. Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence (http://creativecommons.org/licenses/by/3.0). Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 18 May 2020 16:23 |
Last Modified: | 18 May 2020 16:23 |
Status: | Published |
Publisher: | IOP Publishing |
Refereed: | Yes |
Identification Number: | 10.1088/1757-899x/818/1/012020 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:160893 |
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