Bukvic, Alexander J, Crivoi, Dana Georgiana, Garwood, Hollie G et al. (4 more authors) (2020) Tolerant to air σ-alkane complexes by surface modification of single crystalline solid-state molecular organometallics using vapour-phase cationic polymerisation:SMOM@polymer. Chemical communications. D0CC01140A. ISSN 1364-548X
Abstract
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Funding Information: | Funder Grant number EPSRC EP/M024210/2 UNSPECIFIED RPG-2015-447 |
Depositing User: | Pure (York) |
Date Deposited: | 06 Mar 2020 10:20 |
Last Modified: | 17 Dec 2024 00:15 |
Published Version: | https://doi.org/10.1039/d0cc01140a |
Status: | Published online |
Refereed: | Yes |
Identification Number: | 10.1039/d0cc01140a |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:158157 |