Abd El-Wahab, H, El-Meligi, G, Hassaan, MG et al. (2 more authors) (2020) New water-based copolymer nanoparticles and their use as eco-friendly binders for industry of flexographic ink, part I. Pigment & Resin Technology, 49 (3). pp. 239-248. ISSN 0369-9420
Abstract
Purpose: The purpose of this paper is to prepare, characterise and evaluate nano-emulsions of copolymers of various compositions as eco-friendly binders for flexographic ink industry.
Design/methodology/approach: Various nano-emulsions of copolymers were prepared using styrene (St), butyl acrylate (BuAc), acrylic acid (AA) and acrylamide (AAm) monomers by means of a conventional seeded emulsion polymerisation technique, using K2S2O8 as the initiator. The characterisation of the prepared emulsions was performed using Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), gel permeation chromatography (GPC) and transmission electron microscopy (TEM). A selection of copolymers was formulated with pigments and additional ingredients, as water-based flexographic inks. The inks were characterised for their viscosity, pH, degree of dispersion, water resistance and colour density.
Findings: It was found that the low viscosity of the prepared copolymers may reduce the film thickness of the flexographic inks and may also increase the spreading of the ink on the surface. As a result, stable modified polyacrylate-based latex with improved physico-mechanical properties were obtained. The prepared latexes were showed improving and enhancing in water resistance; gloss values, and the print density that ranged from 2.06 to 2.51 and the maximum gloss values (39 and 48) were also obtained. Also, these binders provide excellent adhesion properties for both the pigment particles and the base paper.
Practical implications: This study focuses on the preparation of new water-based copolymer nanoparticles and their use as eco-friendly binders for flexographic ink industry.
Social implications: The ink formulations developed could find use in industrial-scale printing.
Originality/value: Eco-friendly environment ink formulations for printing on paper substrates are novel.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2020, Emerald Publishing Limited. This is an author produced version of a paper published in Pigment & Resin Technology. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | Binders; Acrylate copolymers; industry of inks; nano-emulsion; water-based flexographic inks |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Colour Science (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 19 Feb 2020 09:54 |
Last Modified: | 22 Jul 2021 14:31 |
Status: | Published |
Publisher: | Emerald |
Identification Number: | 10.1108/prt-10-2019-0095 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:157214 |