McKay, Alasdair I., Krämer, Tobias, Rees, Nicholas H. et al. (4 more authors) (2017) Formation of a σ-alkane complex and a molecular rearrangement in the solid-State:[Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]. Organometallics. pp. 22-25. ISSN 0276-7333
Abstract
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016 American Chemical Society |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 03 Jan 2020 12:40 |
Last Modified: | 16 Oct 2024 16:17 |
Published Version: | https://doi.org/10.1021/acs.organomet.6b00645 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1021/acs.organomet.6b00645 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:155090 |
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Filename: acs.organomet.6b00645.pdf
Description: Formation of a σ‑alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2 :η2 ‑C7H12)][BArF 4]
Licence: CC-BY 2.5