Martínez-Martínez, Antonio J., Rees, Nicholas H. and Weller, Andrew S. orcid.org/0000-0003-1646-8081 (2019) Reversible Encapsulation of Xenon and CH2Cl2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM). Angewandte Chemie - International Edition. pp. 16873-16877. ISSN 1433-7851
Abstract
Reversible encapsulation of CH2Cl2 or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy2PCH2PCy2)(NBD)][BArF4] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including 129Xe SSNMR. Non-covalent interactions with the -CF3 groups, and hydrophobic channels formed, of [BArF4]− anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2019 The Authors |
Keywords: | encapsulation,rhodium,single-crystal to single-crystal,solid-state chemistry,xenon |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 03 Jan 2020 11:40 |
Last Modified: | 23 Oct 2024 00:10 |
Published Version: | https://doi.org/10.1002/anie.201910539 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201910539 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:155074 |
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Description: Reversible Encapsulation of Xenon and CH2Cl2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)
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