Piras, Carmen Cristina orcid.org/0000-0002-7128-2979, Slavik, Petr orcid.org/0000-0002-3326-6169 and Smith, David Kelham orcid.org/0000-0002-9881-2714 (2020) Self-Assembling Supramolecular Hybrid Hydrogel Beads. Angewandte Chemie International Edition. pp. 853-859. ISSN 1433-7851
Abstract
With the goal of imposing shape and structure on supramolecular gels, we combine a low molecular weight gelator (LMWG) with the polymer gelator (PG) calcium alginate in a hybrid hydrogel. By imposing thermal and temporal control of the orthogonal gelation methods, the system either forms an extended inter-penetrating network or core-shell structured gel beads – a rare example of a supramolecular gel formulated inside discrete gel spheres. The self-assembled LMWG retains its unique properties within the beads, such as remediating Pd(II) and reducing it in situ to yield catalytically-active Pd(0) nanoparticles. A single PdNP-loaded gel bead can catalyse the Suzuki-Miyaura reaction, constituting a simple and easy-to-use reaction dosing form. These unique shaped and structured LMWG-filled gel beads are a versatile platform technology, with great potential in a range of applications.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2019 The Authors. |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Funding Information: | Funder Grant number EPSRC EP/P03361X/1 |
Depositing User: | Pure (York) |
Date Deposited: | 07 Nov 2019 15:10 |
Last Modified: | 21 Jan 2025 17:43 |
Published Version: | https://doi.org/10.1002/anie.201911404 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201911404 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:153230 |
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Description: Self-Assembling Supramolecular Hybrid Hydrogel Beads
Licence: CC-BY 2.5