Galadzhun, I orcid.org/0000-0002-0512-3830, Capel Berdiell, I orcid.org/0000-0003-3828-7097, Shahid, N orcid.org/0000-0002-8090-7619 et al. (1 more author) (2019) An Iron(II) Coordination Polymer of a Triazolyl Tris-Heterocycle Showing a Spin State Conversion Triggered by Loss of Lattice Solvent. CrystEngComm, 21 (42). pp. 6321-6504. ISSN 1466-8033
Abstract
Solvated crystals of “[FeL2][BF4]2·H2O” (L = 2-(1,2,4-triazol-1-yl)-6-(pyrazol-1-yl)pyridine) contain a 1D coordination polymer, [Fe(μ-L)2{Fe(OH2)22L2}][BF4]4. Two iron environments linked by κ1:κ3,μ-L ligands alternate in the chains, Fe(1) being coordinated by two tridentate L ligands and Fe(2) by four monodentate L and two water molecules. Fe(1) is low-spin in a freshly prepared crystal at 150 K, but gradually converts to a high-spin form when that crystal was measured at higher temperatures. Magnetic data imply this is triggered by loss of ca half a lattice water molecule during the experiment, rather being a thermal spin-crossover.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2019. This is an author produced version of a journal article published in CrystEngComm. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) |
Funding Information: | Funder Grant number Leverhulme Trust RPG-2015-095 |
Depositing User: | Symplectic Publications |
Date Deposited: | 11 Oct 2019 11:49 |
Last Modified: | 17 Dec 2024 14:52 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C9CE01496A |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:152004 |