James, Michael J. orcid.org/0000-0003-2591-0046, Strieth-Kalthoff, Felix, Sandfort, Frederik et al. (3 more authors) (2019) Visible-Light-Mediated Charge Transfer Enables C−C Bond Formation with Traceless Acceptor Groups. Chemistry - A European Journal. pp. 8240-8244. ISSN 1521-3765
Abstract
The development and application of traceless acceptor groups in photochemical C−C bond formation is described. This strategy was enabled by the photoexcitation of electron donor–acceptor (EDA) complexes with visible light. The traceless acceptors, which were readily prepared from amino acid and peptide feedstocks, could be used to alkylate a wide range of heteroarene and enamine donors under metal- and peroxide-free conditions. The crucial role of the EDA complexes in the mechanism of these reactions was explored through combined experimental and computational studies.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details. |
Keywords: | amino acids,C−C bond formation,donor–acceptor systems,traceless acceptors,visible light |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 07 Oct 2019 15:20 |
Last Modified: | 07 Feb 2025 00:26 |
Published Version: | https://doi.org/10.1002/chem.201901397 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1002/chem.201901397 |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:151868 |