Kamaluddin, S., García-Lodeiro, I. and Kinoshita, H. orcid.org/0000-0001-8805-1774 (2019) Strontium in phosphate-modified calcium aluminate cement. Key Engineering Materials, 803. pp. 341-345. ISSN 1013-9826
Abstract
Cements have been used to encapsulate low and intermediate level radioactive wastes. Here, phosphate-modified calcium aluminate (CAP) cement is explored as an encapsulant for strontium radioanuclide-containing wastes. Electron microscopy indicates strontium chloride, used in place of strontium radionuclides, increases porosity in CAP possibly due to increased viscosity of CAP cement during mixing. X-ray diffraction analysis detects formation of halite phase suggesting strontium chloride reacts with cement to form sodium chloride not usually detected in CAP systems as well as formation of an amorphous phase in CAP cement when thermally treated at 90°C.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2019 Trans Tech Publications. |
Keywords: | CAP Cement; Concrete Durability; Nuclear Waste Encapsulation; Nuclear Waste Interaction; Strontium |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Engineering (Sheffield) > Department of Materials Science and Engineering (Sheffield) |
Funding Information: | Funder Grant number ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL (EPSRC) UNSPECIFIED ENGINEERING AND PHYSICAL SCIENCE RESEARCH COUNCIL (EPSRC) EP/N013530/1 |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 26 Jul 2019 11:44 |
Last Modified: | 07 Aug 2019 13:31 |
Status: | Published |
Publisher: | Trans Tech Publications |
Refereed: | Yes |
Identification Number: | 10.4028/www.scientific.net/kem.803.341 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:149013 |