Adams, H., Grimes, L., Morris, M.J. orcid.org/0000-0001-8802-9147 et al. (1 more author) (2018) Dithiolene transfer to the molybdenum nitrosyl complex [CpMo(CO)2(NO)]: Formation of bimetallic complexes. Journal of Organometallic Chemistry, 877. pp. 73-79. ISSN 0022-328X
Abstract
The reaction of the nitrosyl complex [CpMo(CO)2(NO)] (Cp = η-C5H5) with the nickel dithiolene complex [Ni(S2C2Ph2)2] produces the expected dimolybdenum complex [Mo2(NO)2(μ-S2C2Ph2)2Cp2], but only as a minor product (13% yield). The major product (41%) consists of two separable isomers of the tetranuclear complex [Mo2Ni2(NO)2(μ-S2C2Ph2)4Cp2], which comprises two CpMo(NO)Ni(S2C2Ph2)2units joined through bridging sulfur atoms. The isomers differ in the orientation of one dimeric unit in relation to the other. All three compounds have been structurally characterised.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2018 Elsevier. This is an author produced version of a paper subsequently published in Journal of Organometallic Chemistry. Uploaded in accordance with the publisher's self-archiving policy. Article available under the terms of the CC-BY-NC-ND licence (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
Keywords: | Molybdenum; Nickel; Nitrosyl; Dithiolene; Cyclopentadienyl |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 20 Nov 2018 11:50 |
Last Modified: | 26 Sep 2019 00:40 |
Published Version: | https://doi.org/10.1016/j.jorganchem.2018.09.021 |
Status: | Published |
Publisher: | Elsevier |
Refereed: | Yes |
Identification Number: | 10.1016/j.jorganchem.2018.09.021 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:138788 |
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