Coubrough, HM orcid.org/0000-0003-2526-9252, van der Lubbe, SCC, Hetherington, K et al. (5 more authors) (2019) Supramolecular Self‐Sorting Networks using Hydrogen‐Bonding Motifs. Chemistry - A European Journal, 25 (3). pp. 785-795. ISSN 0947-6539
Abstract
A current objective in supramolecular chemistry is to mimic the transitions between complex self‐sorted systems that represent a hallmark of regulatory function in nature. In this work, a self‐sorting network, comprising linear hydrogen motifs, was created. Selecting six hydrogen‐bonding motifs capable of both high‐fidelity and promiscuous molecular recognition gave rise to a complex self‐sorting system, which included motifs capable of both narcissistic and social self‐sorting. Examination of the interactions between individual components, experimentally and computationally, provided a rationale for the product distribution during each phase of a cascade. This reasoning holds through up to five sequential additions of six building blocks, resulting in the construction of a biomimetic network in which the presence or absence of different components provides multiple unique pathways to distinct self‐sorted configurations.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
Keywords: | biomimetic chemistry; hydrogen bonding; molecular recognition; self-sorting; supramolecular chemistry |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 01 Nov 2018 11:53 |
Last Modified: | 25 Jun 2023 21:34 |
Status: | Published |
Publisher: | Wiley |
Identification Number: | 10.1002/chem.201804791 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:138057 |
Commentary/Response Threads
- Coubrough, HM, van der Lubbe, SCC, Hetherington, K, Minard, A, Pask, C, Howard, MJ, Fonseca Guerra, C and Wilson, AJ Supramolecular Self‐Sorting Networks using Hydrogen‐Bonding Motifs. (deposited 01 Nov 2018 11:53) [Currently Displayed]
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