Cosgrove, SC, Douglas, GE, Raw, SA et al. (1 more author) (2018) Continuous Flow for the Photochemical C‐H Amination of Arenes. ChemPhotoChem, 2 (10). pp. 851-854. ISSN 2367-0932
Abstract
The direct C−H amination of arenes by aminium radicals generated by photolysis of N‐chloroamines is demonstrated under continuous flow conditions. The reactions proceed with comparable efficiency to small scale batch processes but are superior to larger scale batch operations. The continuous generation of the N‐chloroamine from the amine precursor can be integrated into the process, facilitating the continuous direct conversion of secondary amines to their arylated derivatives.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Cosgrove, S., Douglas, G., Raw, S. and Marsden, S. (2018), Continuous Flow for the Photochemical C‐H Amination of Arenes. ChemPhotoChem. Accepted Author Manuscript., which has been published in final form at https://doi.org/10.1002/cptc.201800105. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | amination; arylamines; continuous photochemistry; flow chemistry; radical |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 23 Jul 2018 12:49 |
Last Modified: | 18 Jul 2019 00:41 |
Status: | Published |
Publisher: | Wiley-VCH |
Identification Number: | 10.1002/cptc.201800105 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:133609 |