Thorp-Greenwood, FL orcid.org/0000-0001-6228-2056, Berry, GT, Boyadjieva, SS et al. (2 more authors) (2018) 2D networks of metallo-capsules and other coordination polymers from a hexapodal ligand. CrystEngComm, 20 (28). pp. 3939-4060. ISSN 1466-8033
Abstract
The hexapodal ligand hexakis(isonicotinoyl)cyclotricatechylene (L1) belonging to the cyclotriveratrylene family of host-molecules has been synthesised and used in the assembly of a series of coordination polymer materials with Re(I), Co(II), Cu(II), Ni(II) and Ag(I) salts. Single crystal structures of the coordination polymers [Re3(L1)2Br3(CO)3] 1, and an isomorphic [M3L2] series where M = Co, Cu or Ni, reveal 2D framework structures with a simplified topology of 36 or hxl. These are composed of M6(L1)2 metallo-cages linked together in a pair-wise fashion through each metal centre. Compound 1 is a rare example of a rhenium coordination polymer and was investigated for guest uptake from solution, complexing I2. The mixed-ligand species [Cu2(L1)(CF3CO2)3(isonicotinate)] forms a (3,4,5)-connected 2D coordination polymer, while [Ag2(L1)(DMF)2]·2BF4·2(H2O)·6(DMF) features a 2D network of (3,6)-connectivity and with kagome dual (kgd) topology.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | (c) The Royal Society of Chemistry 2018, This is an author produced version of a paper published in CrystEngComm. Uploaded in accordance with the publisher's self-archiving policy.Crown Copyright © 2019 Published by Elsevier B.V. This is an author produced version of a paper published in Journal of Hydrology. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 22 Jun 2018 14:12 |
Last Modified: | 16 Dec 2024 15:32 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C8CE00806J |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:132428 |