Zhao, Y, Feng, J, Hong, L et al. (3 more authors) (2018) Simple surface-assisted formation of palladium nanoparticles on polystyrene microspheres and their application in catalysis. Inorganic Chemistry Frontiers (5). pp. 1133-1138. ISSN 2052-1545
Abstract
A facile and green approach has been developed for fabricating well-dispersed palladium nanoparticles (Pd NPs) supported on the surface of poly(N-vinylpyrrolidone) (PVP)-stabilized polystyrene (PS) microspheres. The strategy harnesses the reducing ability of PVP and the affinity between PVP and Pd NPs to achieve in situ surface-assisted growth of small noble metal NPs on the PS microspheres, without involving any additional stabilizer or reducing agent. The stabilizer-free formation contributes to the superior availability and accessibility of active sites for catalysis. The resulting PS/Pd composite particles have demonstrated excellent catalytic performance in the probe reaction of 4-nitrophenol reduction. As far as we know, this approach has been the first straightforward in situ deposition of Pd NPs on the PS microspheres, obviating surface treatment and the use of an exogenous reducing agent or a stabilizer. Furthermore, it is extendable to the fabrication of other composite systems, PS/Ag composite particles for example.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | (c) The Royal Society of Chemistry 2018, This is a author approved manuscript of a paper published in Inorganic Chemistry Frontiers. Uploaded in accordance with the publisher's self-archiving policy. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Physics and Astronomy (Leeds) > Molecular & Nanoscale Physics |
Depositing User: | Symplectic Publications |
Date Deposited: | 12 Apr 2018 08:53 |
Last Modified: | 08 Mar 2019 01:38 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C8QI00085A |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:129492 |