Raza, MA, Westwood, A orcid.org/0000-0002-5815-0429 and Stirling, C (2018) Graphite nanoplatelet/rubbery epoxy composites as adhesives and pads for thermal interface applications. Journal of Materials Science: Materials in Electronics, 29 (10). pp. 8822-8837. ISSN 0957-4522
Abstract
Composites of graphite nanoplatelets (GNPs) and rubbery epoxy (RE) resins as adhesives and pads are evaluated as thermal interface materials (TIM). GNP-15 and GNP-5 (15 and 5 µm across, respectively) were loaded in RE by 3-roll milling to produce GNP/RE composites. The role of composite processing techniques on the texture, thermal and electrical conductivities and compression properties of composites was studied and compared. Scanning electron microscopy revealed uniform dispersion of GNPs in RE, regardless of loading and X-ray diffraction texture measurement showed less platelet alignment in the composites at low loadings. Thermal conductivities of 20 wt% GNP-15/RE (3.29 W/m K) and 35 wt% GNP-5/RE composite (2.36 W/m K) were both significantly higher than pure RE (0.17 W/m K). GNP/RE retained good compliance, compressive moduli at 20 wt% loading being comparable to commercial BN/silicone TIM. Although thermal contact resistance of GNP/RE was higher than for commercial paste, its interfacial thermal transport outperformed GNP/silicone (due to RE’s strongly adhesive nature) and, across thick bond lines, outperformed reported GNP-pastes. The 20 wt% GNP-15/RE thermal pad had significantly lower thermal contact resistance than other GNP/RE pads. This decreased with increasing applied pressure, being comparable to commercial BN/silicone pad. GNP/RE composites are thus promising candidates for thermal interface adhesives and pads.
Metadata
Item Type: | Article |
---|---|
Authors/Creators: |
|
Copyright, Publisher and Additional Information: | (c) 2018, Springer Science+Business Media, LLC, part of Springer Nature. This is a post-peer-review, pre-copyedit version of an article published in Journal of Materials Science: Materials in Electronics. The final authenticated version is available online at: https://doi.org/10.1007/s10854-018-8900-z. |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 19 Mar 2018 16:41 |
Last Modified: | 15 Mar 2019 01:38 |
Status: | Published |
Publisher: | Springer Nature |
Identification Number: | 10.1007/s10854-018-8900-z |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:128611 |