Glover, PWJ orcid.org/0000-0003-1715-5474 (2018) Modelling pH-Dependent and Microstructure-Dependent Streaming Potential Coefficient and Zeta Potential of Porous Sandstones. Transport in Porous Media, 124 (1). pp. 31-56. ISSN 0169-3913
Abstract
In this paper, we have significantly modified an existing model for calculating the zeta potential and streaming potential coefficient of porous media and tested it with a large, recently published, high-quality experimental dataset. The newly modified model does not require the imposition of a zeta potential offset but derives its high salinity zeta potential behaviour from Stern plane saturation considerations. The newly modified model has been implemented as a function of temperature, salinity, pH, and rock microstructure both for facies-specific aggregations of the new data and for individual samples. Since the experimental data include measurements on samples of both detrital and authigenic overgrowth sandstones, it was possible to model and test the effect of widely varying microstructural properties while keeping lithology constant. The results show that the theoretical model represents the experimental data very well when applied to model data for a particular lithofacies over the whole salinity, from 10¯⁵ to 6.3 mol/dm³, and extremely well when modelling individual samples and taking individual sample microstructure into account. The new model reproduces and explains the extreme sensitivity of zeta and streaming potential coefficient to pore fluid pH. The low salinity control of streaming potential coefficient by rock microstructure is described well by the modified model. The model also behaves at high salinities, showing that the constant zeta potential observed at high salinities arises from the development of a maximum charge density in the diffuse layer as it is compressed to the thickness of one hydrated metal ion.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Author(s) 2018. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
Keywords: | Microstructure, porosity, streaming potential, zeta potential, electrical rock properties |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Earth and Environment (Leeds) > Institute for Applied Geosciences (IAG) (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 07 Mar 2018 14:37 |
Last Modified: | 03 Dec 2018 20:06 |
Status: | Published |
Publisher: | Springer Nature |
Identification Number: | 10.1007/s11242-018-1036-z |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:128274 |