Baik, S, Zhang, H orcid.org/0000-0002-0169-517X, Kim, YK et al. (2 more authors) (2017) Enhanced adsorption capacity and selectivity towards strontium ions in aqueous systems by sulfonation of CO2 derived porous carbon. RSC Advances, 7 (86). pp. 54546-54553. ISSN 2046-2069
Abstract
Oxygen-enriched carbon materials derived from carbon dioxide were functionalized using sulfonic acid to remove Sr2+ ions from aqueous solutions. Synthesized sulfonated porous carbon materials (PC-SO3H) showed higher adsorption capacity and selectivity towards Sr2+ than non-functionalized porous carbons (PC). The formation of the C-SO3H functional group in PC-SO3H and its ability to proton exchange with Sr2+ was the main contributor to the enhanced performance. The maximum uptake capacity of Sr2+ by PC-SO3H was 18.97 mg g−1, which was 1.74 times greater than PC. PC-SO3H removed 99.9% and 97.6% of Sr2+ from aqueous solutions with initial Sr2+ concentrations of 5 mg L−1 and 10 mg L−1, respectively. Sr2+ adsorption showed rapid kinetics, reaching the adsorption equilibrium within 1 h with high adsorption capacity at equilibrium which is 3.52 times greater than that of PC. Additionally, PC-SO3H selectively adsorbed Sr2+ even in the presence of excess amounts of competing ions. Sulfonation of oxygen-enriched carbon had a significant effect on enhancing the affinity towards Sr2+ and suppressing adsorption towards other competing ions.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2017. This is an open access article, licensed under a Creative Commons Attribution 3.0 Unported License https://creativecommons.org/licenses/by/3.0/ |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Funding Information: | Funder Grant number EPSRC EP/M026426/1 |
Depositing User: | Symplectic Publications |
Date Deposited: | 16 Jan 2018 11:22 |
Last Modified: | 06 Dec 2018 09:54 |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/c7ra09541d |
Related URLs: | |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:126279 |