Shimizu, Seishi orcid.org/0000-0002-7853-1683 and Matubayasi, Nobuyuki (2018) A unified perspective on preferential solvation and adsorption based on inhomogeneous solvation theory. Physica A: Statistical Mechanics and its Applications. pp. 1988-1996. ISSN 0378-4371
Abstract
How cosolvents affects solvation has been revealed through the independent determination of solute-solvent and solute-cosolvent interactions guaranteed by the phase rule. Based on the first principles of inhomogeneous solvation theory, we present here a general matrix theory encompassing both preferential solvation and surface adsorption. The central role of the stability conditions that determine how many excess numbers (surface excesses) are independently determinable, have been clarified from the first principles. The advantage of the inhomogeneous approach has been demonstrated to be in its ease in treating solvation and adsorption in a unified manner, while its disadvantage, for example in membrane dialysis experiments, can be overcome by the inhomogeneous-homogeneous conversion.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © Elsevier Ltd., 2017. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 01 Dec 2017 12:00 |
Last Modified: | 16 Oct 2024 13:55 |
Published Version: | https://doi.org/10.1016/j.physa.2017.11.113 |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1016/j.physa.2017.11.113 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:124761 |