Morales-Serna, JA, Nguyen, BN orcid.org/0000-0002-0254-025X, García-Ríos, E et al. (3 more authors) (2018) Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide. Synthesis, 50 (3). pp. 593-598. ISSN 0039-7881
Abstract
The direct glycosylation of ceramides in supercritical carbon dioxide (scCO₂) successfully proceeded to produce β-glycolipids in high yield and with full stereoselectivity. The reaction is promoted by montmorillonite modified with a superacid (CF₃SO₃H). The value of this protocol was demonstrated in the efficient synthesis of isoglobotrihexosylceramide (iGB3).
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2018 Georg Thieme Verlag Stuttgart · New York. This is an author produced version of a paper published in Synthesis. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | glycosylation; β-glycolipids; iGB3; supercritical carbon dioxide; montmorillonite |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 10 Nov 2017 15:35 |
Last Modified: | 07 Nov 2018 01:38 |
Status: | Published |
Publisher: | Thieme Publishing |
Identification Number: | 10.1055/s-0036-1591515 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:123691 |