Callingham, M., Partridge, B.M. orcid.org/0000-0002-8550-9994, Lewis, L. et al. (1 more author) (2017) Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and imines by alkenyl-to-allyl 1,4-rhodium(I) migration. Angewandte Chemie International Edition, 56 (51). pp. 16352-16356. ISSN 1433-7851
Abstract
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ |
Keywords: | allylation; asymmetric catalysis; imines; isomerization; rhodium |
Dates: |
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Institution: | The University of Sheffield |
Academic Units: | The University of Sheffield > Faculty of Science (Sheffield) > Department of Chemistry (Sheffield) |
Depositing User: | Symplectic Sheffield |
Date Deposited: | 12 Oct 2017 10:36 |
Last Modified: | 15 Dec 2023 15:51 |
Status: | Published |
Publisher: | Wiley |
Refereed: | Yes |
Identification Number: | 10.1002/anie.201709334 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:122407 |