Apps, JFS, Livingston, AG, Parrett, MR et al. (3 more authors) (2014) Racemisation of 1-Arylethylamines with Shvo-type Organoruthenium Catalysts. Synlett, 25 (10). pp. 1391-1394. ISSN 0936-5214
Abstract
Variation of the electronic nature of the tetraphenylcyclopentadienone ligand in organoruthenium complexes influences their utility for racemisation of model chiral amines. Our study highlights the need to balance reactivity and selectivity in the design of racemisation catalysts. Electron-poor Shvo-type catalysts are, at first sight, more effective for racemisation, but yield more by-product; electron-rich complexes are less proficient at racemisation, but lead to less by-product.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | (c) 2014, Georg Thieme Verlag Stuttgart · New York. This is an author produced version of a letter published in Synlett. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | racemisation - amine - alcohol - organoruthenium - DFT |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 28 Feb 2018 09:44 |
Last Modified: | 28 Feb 2018 09:44 |
Status: | Published |
Publisher: | Georg Thieme Verlag |
Identification Number: | 10.1055/s-0033-1341228 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:121533 |