Liu, SY, Mei, DH, Nahil, MA et al. (4 more authors) (2017) Hybrid plasma-catalytic steam reforming of toluene as a biomass tar model compound over Ni/Al₂O₃ catalysts. Fuel Processing Technology, 166. pp. 269-275. ISSN 0378-3820
Abstract
In this study, plasma-catalytic steam reforming of toluene as a biomass tar model compound was carried out in a coaxial dielectric barrier discharge (DBD) plasma reactor. The effect of Ni/Al2O3 catalysts with different nickel loadings (5–20 wt%) on the plasma-catalytic gas cleaning process was evaluated in terms of toluene conversion, gas yield, by-products formation and energy efficiency of the plasma-catalytic process. Compared to the plasma reaction without a catalyst, the combination of DBD with the Ni/Al2O3 catalysts significantly enhanced the toluene conversion, hydrogen yield and energy efficiency of the hybrid plasma process, while significantly reduced the production of organic by-products. Increasing Ni loading of the catalyst improved the performance of the plasma-catalytic processing of toluene, with the highest toluene conversion of 52% and energy efficiency of 2.6 g/kWh when placing the 20 wt% Ni/Al2O3 catalyst in the plasma. The possible reaction pathways in the hybrid plasma-catalytic process were proposed through the combined analysis of both gas and liquid products.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2017 Elsevier B.V. This is an author produced version of a paper published in Fuel Processing Technology. Uploaded in accordance with the publisher's self-archiving policy. This manuscript version is made available under the Creative Commons CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Keywords: | Plasma-catalysis; Non-thermal plasma; Dielectric barrier discharge; Biomass gasification; Tar removal |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 21 Jul 2017 08:30 |
Last Modified: | 02 Aug 2019 12:54 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.fuproc.2017.06.001 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:119312 |