Chow, SY orcid.org/0000-0002-3600-0497, Stevens, MY, Åkerbladh, L et al. (2 more authors) (2016) Mild and Low-Pressure fac -Ir(ppy) 3 -Mediated Radical Aminocarbonylation of Unactivated Alkyl Iodides through Visible-Light Photoredox Catalysis. Chemistry - A European Journal, 22 (27). pp. 9155-9161. ISSN 0947-6539
Abstract
A novel, mild and facile preparation of alkyl amides from unactivated alkyl iodides employing a fac-Ir(ppy)3-catalyzed radical aminocarbonylation protocol has been developed. Using a two-chambered system, alkyl iodides, fac-Ir(ppy)3, amines, reductants, and CO gas (released ex situ from Mo(CO)6), were combined and subjected to an initial radical reductive dehalogenation generating alkyl radicals, and a subsequent aminocarbonylation with amines affording a wide range of alkyl amides in moderate to excellent yields.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Keywords: | amides; carbonylation; photocatalysis; radical reactions |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 12 May 2017 12:21 |
Last Modified: | 30 May 2018 12:28 |
Status: | Published |
Publisher: | Wiley |
Identification Number: | 10.1002/chem.201601694 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:116273 |