Doherty, Simon, Knight, Julian, Backhouse, Thomas et al. (5 more authors) (2017) Highly efficient aqueous phase chemoselective hydrogenation of α,β-unsaturated aldehydes catalysed by phosphine-decorated polymer immobilized IL-stabilized PdNPs. Green Chemistry. pp. 1635-1641. ISSN 1463-9270
Abstract
Phosphino-decorated polymer immobilised ionic liquid phase stabilised palladium nanoparticles (PdNP@PPh2-PIILP) and their PEGylated counterparts (PdNP@PPh2-PEGPIILP) are remarkably active and exceptionally selective catalysts for the aqueous phase hydrogenation of α,β-unsaturated aldehydes, ketones, esters and nitriles with PdNP@PPh2-PEGPIILP giving complete conversion and 100% selectivity for reduction of the C[double bond, length as m-dash]C bond, under mild conditions. This is the most selective PdNP-based system to be reported for the aqueous phase hydrogenation of this class of substrates.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © The Royal Society of Chemistry 2017. This is an author-produced version of the published paper. Uploaded in accordance with the publisher’s self-archiving policy. Further copying may not be permitted; contact the publisher for details |
Keywords: | Palladium,Catalysis,Nanoparticles,GREEN CHEMISTRY |
Dates: |
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Institution: | The University of York |
Academic Units: | The University of York > Faculty of Sciences (York) > Chemistry (York) |
Depositing User: | Pure (York) |
Date Deposited: | 02 May 2017 11:20 |
Last Modified: | 02 Apr 2025 23:10 |
Published Version: | https://doi.org/10.1039/C6GC03528K |
Status: | Published |
Refereed: | Yes |
Identification Number: | 10.1039/C6GC03528K |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:115911 |
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