Piazolo, S orcid.org/0000-0001-7723-8170, Belousova, E, Fontaine, AL et al. (2 more authors) (2017) Trace element homogeneity from micron- to atomic scale: Implication for the suitability of the zircon GJ-1 as a trace element reference material. Chemical Geology, 456. pp. 10-18. ISSN 0009-2541
Abstract
The quality of a chemical reference material relies on the fact that the composition of the material is homogeneous across all scales. A series of different techniques have been used to evaluate the trace element homogeneity of the GJ-1 reference zircon from the micron- to atomic scale. Cathodoluminescence imaging was conducted along with quantitative crystallographic orientation analysis and trace element analysis using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). The nanometre-scale homogeneity was evaluated by analysing five mineral tips using atom probe tomography, which provides atomic scale three dimensional chemical reconstructions with unprecedented spatial resolution. Results show that the GJ-1 reference zircon is homogeneous at all scales, both structurally and chemically. Crystallographic orientation data confirms that this gem quality zircon has no detectable internal crystallographic orientation changes such as crystal-plastic deformation features or cracks. No mineral inclusions were found. Atom probe tomography shows that there is a lack of any chemical clustering or other modes of spatially defined elemental accumulation or depletion for the most abundant trace elements such as Y, Yb and Hf. This finding is supported by LA-ICPMS data revealing homogeneity within the analytical precision. Trace elements of significant abundance include P, Yb, Y, U and Hf, with contents of 30 ± 6, 65 ± 2, 238 ± 5, 284 ± 14 and 6681 ± 57 ppm, respectively. Hence, the GJ-1 zircon used as a reference zircon for UPb and Hf-isotopic studies is also a suitable zircon reference material for trace element analyses.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2017 Published by Elsevier B.V. This is an author produced version of a paper published in Chemical Geology. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | Zircon; Reference material; Trace elements; Atom probe tomography; Nanometre scale; GJ-1 |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Environment (Leeds) > School of Earth and Environment (Leeds) > Inst of Geophysics and Tectonics (IGT) (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 06 Mar 2017 10:07 |
Last Modified: | 03 Mar 2018 01:38 |
Published Version: | https://doi.org/10.1016/j.chemgeo.2017.03.001 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.chemgeo.2017.03.001 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:113252 |