Al-Sayegh, WA, Aljumaiah, O, Andrews, GE orcid.org/0000-0002-8398-1363 et al. (1 more author) (2017) PVC Cable Fire Toxicity using the Cone Calorimeter. In: Harada, K, Matsuyama, K, Himoto, K, Nakamura, Y and Wakatsuki, K, (eds.) Fire Science and Technology 2015. 10th Asia-Oceania Symposium on Fire Science and Technology, 05-07 Oct 2015, Tsukuba, Japan. Springer , pp. 175-182. ISBN 978-981-10-0375-2
Abstract
Electrical cables with PVC sheaths were investigated for their ignition characteristics, heat release and toxic yields using the cone calorimeter. 40 KW/m² was required to get a significant heat release for PVC. A heated Temet Gasmet FTIR was used for the toxic gas analysis. Gas samples were taken from the cone calorimeter diluted exhaust duct and transferred to the FTIR using a 190°C heated sample line, heated pump and filter and a second 190°C heated sample line between the pump and the FTIR. The FTIR measurement zone was also heated at 190°C so that no loss of HCl and other condensable gases occurred. This heated sample system enabled the theoretical HCl yield, based on the chlorine content of PVC, to be measured. This indicated that there were no other significant chlorine products in the well ventilated fires. A peak yield of 0.45 for HCl was found. There were significant yields of the irritant gas acrolein and formaldehyde and acrolein was the most important toxic gas. The PVC sample and the char that remained after the test were analysed using TGA and the results showed that only 41.6% of the chlorine in the sample was lost as HCl in the cone calorimeter test, the rest remained in the char.
Metadata
Item Type: | Proceedings Paper |
---|---|
Authors/Creators: |
|
Editors: |
|
Copyright, Publisher and Additional Information: | © Springer Science+Business Media Singapore 2017. This is an author produced version of a paper published in Fire Science and Technology 2015. The final publication is available at Springer via https://doi.org/10.1007/978-981-10-0376-9_17. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | PVC Cable Fires; Toxic Gases; HCl; Acrolein; Cone Calorimeter |
Dates: |
|
Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemical & Process Engineering (Leeds) |
Funding Information: | Funder Grant number Innovate UK - KTP fkaTechnology Strategy Board (KTP) KTP009259 |
Depositing User: | Symplectic Publications |
Date Deposited: | 26 Feb 2018 14:55 |
Last Modified: | 26 Feb 2018 14:55 |
Status: | Published |
Publisher: | Springer |
Identification Number: | 10.1007/978-981-10-0376-9_17 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:107239 |