Fowler, JM orcid.org/0000-0001-8142-9084, Thorp-Greenwood, FL orcid.org/0000-0001-6228-2056, Warriner, SL orcid.org/0000-0002-7589-6011 et al. (2 more authors) (2016) M12L8 metallo-supramolecular cube with cyclotriguaiacylene-type ligand: spontaneous resolution of cube and its constituent host ligand. Chemical Communications, 52 (56). pp. 8699-8702. ISSN 1359-7345
Abstract
The racemic ligand (±)-tris-(4-methylthiazolyl)cyclotriguaiacylene forms a homochiral crystalline Ag12L8 cube with spontaneous resolution. The ligand itself likewise crystallises in a chirally pure fashion in two clathrate complexes. Ag12L8 is the first example of a cyclotriguaiacylene-type coordination cube and a rare example of a M12L8-type metallo-cube.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016, The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material. |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Inorganic Chemistry (Leeds) The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) > School of Chemistry (Leeds) > Organic Chemistry (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 23 Jun 2016 15:41 |
Last Modified: | 12 Dec 2024 13:46 |
Published Version: | http://dx.doi.org/10.1039/C6CC04130B |
Status: | Published |
Publisher: | Royal Society of Chemistry |
Identification Number: | 10.1039/C6CC04130B |
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Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:101126 |