Richardson, PM, Voice, AM and Ward, IM (2016) NMR Self Diffusion and Relaxation Time Measurements for Poly (vinylidene fluoride) (PVDF) Based Polymer Gel Electrolytes Containing LiBF4 and Propylene Carbonate. Polymer, 97. pp. 69-79. ISSN 0032-3861
Abstract
Polymer gel electrolytes (PGEs) have been prepared using lithium tetrafluoroborate (LiBF4), propylene carbonate (PC) and poly (vinylidene fluoride) (PVDF). Self diffusion coefficients have been measured using pulse field gradient nuclear magnetic resonance (PFG-NMR) for the lithium cation, BF4 anion and solvent molecules using 7Li, 19F and 1H nuclei, respectively. It was found that lithium ion diffusion was slow compared to the much larger fluorinated BF4 anion, which is attributed to a large solvation shell around the lithium ions. The 7Li and 1H diffusion measurements also exhibited two unique environments for the diffusive species. The measurement of NMR transverse relaxation times has confirmed the presence of lithium ions in multiple phases as shown by the diffusion measurements.
Metadata
Item Type: | Article |
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Authors/Creators: |
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Copyright, Publisher and Additional Information: | © 2016, Published by Elsevier Ltd. This is an author produced version of a paper published in Polymer. Uploaded in accordance with the publisher's self-archiving policy. |
Keywords: | NMR; Diffusion; Polymer gel electrolyte; LiBF4; Transverse relaxation; PVDF |
Dates: |
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Institution: | The University of Leeds |
Academic Units: | The University of Leeds > Faculty of Engineering & Physical Sciences (Leeds) |
Depositing User: | Symplectic Publications |
Date Deposited: | 15 Jun 2016 15:59 |
Last Modified: | 30 Jun 2020 14:50 |
Published Version: | http://dx.doi.org/10.1016/j.polymer.2016.03.074 |
Status: | Published |
Publisher: | Elsevier |
Identification Number: | 10.1016/j.polymer.2016.03.074 |
Open Archives Initiative ID (OAI ID): | oai:eprints.whiterose.ac.uk:100044 |