A Novel Technology for Complex Rheological Measurements

As the UK nuclear industry embarks on a second phase of nuclear power generation, the industry is faced with numerous sludge and slurry challenges associated with the decommissioning and clean-up of historical nuclear sites. The remediation of Sellafield, the largest nuclear site in the UK, is anticipated to cost GBP 53bn over the next 100 years. Substantial cost is associated with the clean-up, transfer and safe storage of legacy particulate wastes encountered in ponds, silos, highly active storage tanks and many more large tanks on site. To develop suitable design strategies for the mobilization and transfer of sludge, the rheology of the sludge should be accurately determined. The current work demonstrates the use of a Quartz Crystal Microbalance to measure sludge rheology, specifically the shear yield stress. The device is simple to operate with no mechanical parts, small and portable enabling deployment into limited access areas, and eliminates the need for operator sampling and laboratory measurement. The measurement principle relates to the resonance frequency and motional resistance of a piezo-electric sensor as the sensor is submerged in the desired test material. The air-to-sample frequency and resistance shifts are shown to correlate with the shear yield stress of the suspension as measured by conventional vane viscometry. As the particle network stiffens (increased yield stress), the sensor motional resistance and its resonant frequency become more positive These characteristic responses and their correlation to the shear yield stress have been confirmed for a range of particle suspensions.